Influence of size, shape and core-shell interface on surface plasmon resonance in Ag and Ag@MgO nanoparticle films deposited on Si/SiOx

This is an Open Access article under the terms of the Creative Commons Attribution License.-- et al.Ag and Ag@MgO core-shell nanoparticles (NPs) with a diameter of d = 3-10 nm were obtained by physical synthesis methods and deposited on Si with its native ultrathin oxide layer SiOx (Si/SiOx). Scanning electron microscopy and transmission electron microscopy (TEM) images of bare Ag NPs revealed the presence of small NP aggregates caused by diffusion on the surface and agglomeration. Atomic resolution TEM gave evidence of the presence of crystalline multidomains in the NPs, which were due to aggregation and multitwinning occurring during NP growth in the nanocluster source. Co-deposition of Ag NPs and Mg atoms in an oxygen atmosphere gave rise to formation of a MgO shell matrix surrounding the Ag NPs. The behaviour of the surface plasmon resonance (SPR) excitation in surface differential reflectivity (SDR) spectra with p-polarised light was investigated for bare Ag and Ag@MgO NPs. It was shown that the presence of MgO around the Ag NPs caused a red shift of the plasmon excitation, and served to preserve its existence after prolonged (five months) exposure to air, realizing the possibility of technological applications in plasmonic devices. The Ag NP and Ag@MgO NP film features in the SDR spectra could be reproduced by classical electrodynamics simulations by treating the NP-containing layer as an effective Maxwell Garnett medium. The simulations gave results in agreement with the experiments when accounting for the experimentally observed aggregation.This work has been supported by the Italian MIUR under grant FIRB RBAP115AYN (Oxides at the nanoscale: multifunctionality and applications).Peer Reviewe

SUSTAINABLE TRANSPORT – CITY OF SÃO PAULO, EAST RADIAL CORRIDOR

O desenvolvimento sustentável das cidades passa necessariamente pela sustentabilidade dos deslocamentos de pessoas e cargas.Estes estão intimamente ligados à qualidade da utilização do espaço/tempo das pessoas na interação com a Cidade. Como objeto do estudo, vamos caracterizar a atual situação do transporte no Corredor Radial Leste e indicar caminhos para a melhoria destes deslocamentos com a redução da emissão de poluentes.The sustainable development of cities involves necessarily the aspects of sustainability of people and cargo movements.These are closely linked to the usage quality of people’s space/time interacting with the City. As the focus of study, it will be characterized the current transport situation in the East Radial Corridor and suggested ways to improve the movements with reduction of pollutant emissions

Future Urban Scenes Generation Through Vehicles Synthesis

In this work we propose a deep learning pipeline to predict the visual future appearance of an urban scene. Despite recent advances, generating the entire scene in an end-to-end fashion is still far from being achieved. Instead, here we follow a two stages approach, where interpretable information is included in the loop and each actor is modelled independently. We leverage a per-object novel view synthesis paradigm; i.e. generating a synthetic representation of an object undergoing a geometrical roto-translation in the 3D space. Our model can be easily conditioned with constraints (e.g. input trajectories) provided by state-of-the-art tracking methods or by the user itself. This allows us to generate a set of diverse realistic futures starting from the same input in a multi-modal fashion. We visually and quantitatively show the superiority of this approach over traditional end-to-end scene-generation methods on CityFlow, a challenging real world dataset

Influence of size, shape and core\u2013shell interface on surface plasmon resonance in Ag and Ag@MgO nanoparticle films deposited on Si/SiOx

Ag and Ag@MgO core-shell nanoparticles (NPs) with a diameter of d = 3-10 nm were obtained by physical synthesis methods and deposited on Si with its native ultrathin oxide layer SiOx (Si/SiOx). Scanning electron microscopy and transmission electron microscopy (TEM) images of bare Ag NPs revealed the presence of small NP aggregates caused by diffusion on the surface and agglomeration. Atomic resolution TEM gave evidence of the presence of crystalline multidomains in the NPs, which were due to aggregation and multitwinning occurring during NP growth in the nanocluster source. Co-deposition of Ag NPs and Mg atoms in an oxygen atmosphere gave rise to formation of a MgO shell matrix surrounding the Ag NPs. The behaviour of the surface plasmon resonance (SPR) excitation in surface differential reflectivity (SDR) spectra with p-polarised light was investigated for bare Ag and Ag@MgO NPs. It was shown that the presence of MgO around the Ag NPs caused a red shift of the plasmon excitation, and served preserve its existence after prolonged (five months) exposure to air, realizing the possibility of technological applications in plasmonic devices. The Ag NP and Ag@MgO NP film features in the SDR spectra could be reproduced by classical electrodynamics simulations by treating the NP-containing layer as an effective Maxwell Garnett medium. The simulations gave results in agreement with the experiments when accounting for the experimentally observed aggregation

The comparison of the proteomic profile of periodontal pocket and of corresponding gingival crevicular fluid to study periodontal disease biomarkers: feasibility study. biomarkers: feasibility study

Aim: Periodontitis is a set of inflammatory disorders characterized by periodontal attachment loss by periodontal pocket development, leading to tooth loss if remain untreated. The etiology and progress of periodontal disease is complex and remains mostly unknown. So, periodontal disease therapy has considerable limitations. The easy, reliable and correct early detection and control of the disease, markedly reduces biological and social costs. However, the diagnosis of periodontitis is established exclusively by clinical criteria based on probing to assess periodontal pockets, which are the pathognomonic expression of periodontal disease. The -omic sciences acquired substantial significance of late years and, in particular, proteomic seemed to be the more promising in this initial stage. Most proteomic analysis regarding periodontal diseases have been performed on saliva, crevicular fluid samples, peripheral blood or periodontal plaque samples which are more easily to harvest than the tissue of the periodontal pocket. However, they failed to provide reliable results for clinical applications. On the contrary, very few studies were directly performed on the periodontal pocket. So, the aim of this study was to compare the proteomic profile of interproximal pocket tissues with that of GCF, and to analyze if they show a significant similarity in the proteomic profile. Methods: in this preliminary study, we enrolled 3 healthy subjects affected by severe periodontitis needing of periodontal surgery. Immediately before the surgery, GCF samples were taken by means of filter paper strips positioned in the gingival sulcus correspondent to periodontal pockets. Then, periodontal pocket tissue, harvested during surgery, was adequately stored for proteomic analyses. All samples were immediately frozen at \u201380\ub0C and maintained until further analysis. Tissue samples were mechanically disrupted and incubated in lysis buffer, while GCF was obtained incubating the collecting paper in phosphate buffered. In both cases, after centrifugation, the supernatant was precipitated in cold acetone overnight and protein content were pelleted by centrifugation and then dissolved in a rehydration buffer. Mono-dimensional gel electrophoresis was used to separate protein content. After staining gel images were acquired and compared. Liquid chromatography coupled to mass spectrometry (LC-MS/MS) analysis was performed to allow protein spot identification. Results: 1-DE gels from periodontal pocket tissue and the correspondent GCF was analyzed by software Quantity One. Almost the same qualitative protein expression profile in pocket tissue and GCF was found from each patient. However, no statistical significant correlation between the quantitative proteomic profile of pocket tissue and GCF was found. Only one band (that of K immunoglobulin) resulted statistically significant between GCF and pocket tissue proteome in all patients. Conclusions To date, this is the first study comparing the proteome of periodontal pocket tissue and corresponding GCF. The periodontal pocket and the GCF are similar as proteomic networks, but the protein network of the periodontal pocket does not influence significantly the GCF protein network and the other way around. So, with the limitations of this study, the preliminary results seem to indicate that the GCF does not seem suitable to study on the pathogenesis of periodontal disease explaining the reason for the failure of studies based only on GCF to control the periodontal disease in real-time

A Novel Vibrational Spectroscopy Using Spintronic-Plasmonic Antennas: Magneto-Refractive Surface-Enhanced Infrared Absorption

We present experimental and theoretical results of the molecular sensing performance of a novel platform based on magnetic modulation of surface-enhanced infrared absorption spectroscopy. For this, we study the effect that molecular infrared vibrations of a PMMA layer have on the optical and magneto-refractive response of spintronic antennas. Specifically, a periodic array of rods is fabricated from giant-magneto-resistance Au/Ni81Fe19 metallic multilayers, and the effect of depositing a layer of PMMA on top of the array is investigated from both experimental and theoretical points of view. We find that the relative changes induced by the infrared vibrations of PMMA on the magneto-refractive signal are larger than the relative changes induced on the optical transmission. This result indicates that the magneto-refractive response is more sensitive to the excitation of molecular vibrations than the optical response and fosters the development of a novel type of an infrared sensing technique based on spintronic antennas: Magneto-Refractive Surface-Enhanced Infrared Absorption (SEIRA) Spectroscopy.We acknowledge financial support from MINECO through projects AMES (No. MAT 2014-58860-P), Quantum Spin Plasmonics (No. FIS2015-72035-EXP), and MIRRAS (No. MAT2017-84009-R) and Comunidad de Madrid (CM) through project SINOXPHOS-CM (No. S2018/BAA-4403). We acknowledge the service from the MiNa Laboratory at IMN and funding from MINECO under Project No. CSIC13-4E-1794 and from CM under Project No. S2013/ICE-2822 (Space-Tec), both with support from EU (FEDER, FSE). L.B., N.Z., and J.A. acknowledge support from the Department of Education, Research and Universities of the Basque Government through Project Ref. No. IT-1164-19, the Department of Industry of the Basque Government through Project No. KK-2018/00001, and the Spanish MICIN through Project Ref. No. PID2019-107432GB-I0